\(m_{Br_2}=80g\Rightarrow n_{Br_2}=0,5mol\)

\(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)

0,5         0,5

\(n_{hh}=\dfrac{28}{22,4}=1,25mol\)

\(\Rightarrow n_{CH_4}=1,25-0,5=0,75mol\)

\(\%V_{CH_4}=\dfrac{0,75}{1,25}\cdot100\%=60\%\)

\(\%V_{C_2H_4}=100\%-60\%=40\%\)

a, Cho hỗn hợp khí CH₄ và C₂H₄ qua dung dịch Br₂ dư chỉ có C₂H₄ tham gia phản ứng. PTHH: \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)

b, \(n_{Br_2}=\dfrac{m_{Br_2}}{M_{Br_2}}=\dfrac{64}{160}=0,4(mol)\)

Theo PTHH: \(n_{C_2H_4}=n_{Br_2}=0,4(mol)\)

\(V_{C_2H_4}=n_{C_2H_4}.22,4=0,4.22,4=8,96(l)\)

Phần trăm của khí C₂H₄ trong hỗn hợp ban đầu là: \(\%V_{C_2H_4}=\dfrac{V_{C_2H_4}}{V_hh}.100\%=\dfrac{8,96}{11,2}.100\%=80\%\)

Phần trăm của khí CH₄ trong hỗn hợp ban đầu là: 

\(\%V_{CH_4}=100\%-\%V_{C_2H_4}=100\%-80\%=20\%\)

nBr2 = 16 / 160 = 0.1 (mol) 

nhh = 5.6 / 22.4 = 0.25 (mol ) 

C2H4 + Br2 => C2H4Br2 

0.1..........0.1

%VC2H4 = 40% 

\(a)C_2H_4 + Br_2 \to C_2H_4Br_2\\ b) n_{C_2H_4} = n_{Br_2} = \dfrac{80}{160} = 0,5(mol)\\ \Rightarrow V_{C_2H_4} = 0,5.22,4 = 11,2(lít)\\ V_{CH_4} = 67,2 -11,2 = 56(lít)\\ c) \%V_{CH_4} = \dfrac{56}{67,2}.100\% = 83,33\%\\ \%V_{C_2H_4} = 100\% -83,33\% = 16,67\%\)

a, Ta có: \(n_{CH_4}+n_{C_2H_4}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\left(1\right)\)

\(16n_{CH_4}+28n_{C_2H_4}=3\left(2\right)\)

Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}n_{CH_4}=0,1\left(mol\right)\\n_{C_2H_4}=0,05\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}\%m_{CH_4}=\dfrac{0,1.16}{3}.100\%\approx53,33\%\\\%m_{C_2H_4}\approx46,67\%\end{matrix}\right.\)

- Ở cùng điều kiện nhiệt độ và áp suất, % số mol cũng là %V.

\(\Rightarrow\left\{{}\begin{matrix}\%V_{CH_4}=\dfrac{0,1}{0,15}.100\%\approx66,67\%\\\%V_{C_2H_4}\approx33,33\%\end{matrix}\right.\)

b, PT: \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)

Có: m _tăng = m_C2H4 = 0,05.28 = 1,4 (g)

a) \(n_{hh}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)

Gọi \(\left\{{}\begin{matrix}n_{CH_4}=a\left(mol\right)\\n_{C_2H_4}=b\left(mol\right)\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}a+b=0,15\\16a+28b=3\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,1\\b=0,05\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}\%V_{CH_4}=\dfrac{0,1}{0,15}.100\%=66,67\%\\\%V_{C_2H_4}=100\%-66,67\%=33,33\%\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}\%m_{CH_4}=\dfrac{0,1.16}{3}.100\%=53,33\%\\\%m_{C_2H_4}=100\%-53,33\%=46,67\%\end{matrix}\right.\)

b) \(m=m_{C_2H_4}=0,05.28=1,4\left(g\right)\)

PTHH: \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)

Ta có: \(n_{Br_2}=\dfrac{16}{160}=0,1\left(mol\right)=n_{C_2H_4}\)

\(\Rightarrow\%V_{C_2H_4}=\dfrac{0,1\cdot22,4}{8,96}=25\%\) \(\Rightarrow\%V_{CH_4}=75\%\)

VCH4 = 2,24 (l)

VC2H4 = 8,96 - 2,24 = 6,72 (l)

nC2H4 = 6,72/22,4 = 0,3 (mol)

PTHH: C2H4 + Br2 -> C2H4Br2 

Mol: 0,3 ---> 0,3

mBr2 = 0,3 . 160 = 48 (g)

ta có :

nBr2=\(\dfrac{16}{160}=0,1mol\)

C2H4+Br2->C2H4Br2

0,1------0,1

=>VC2H4=0,1.22,4=2,24l

=>VCH4=3,36l->n CH4=0,15 mol

->%VC2H4=\(\dfrac{2,24}{5,6}.100\)=40%

=>%VCH4=60%

c)

CH4+2O2-to>CO2+2H2O

0,15---------------0,15

C2H4+3O2--to>2CO2+2H2O

0,1--------------------0,2
=>m CaCO3=0,35.100=35g